Research Article
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Year 2023, Volume: 36 Issue: 3, 1001 - 1020, 01.09.2023
https://doi.org/10.35378/gujs.1011056

Abstract

References

  • [1] Simsek, V., "Application of mercury porosimetry to three dimensional(3D) stochastic network model and researching network size effect on structure of porous media", MSc Thesis, Gazi University Graduate School of Natural and Applied Sciences, (2008).
  • [2] Huysmans, M., Dassargues, A., "The effect of heterogeneity of diffusion parameters on chloride transport in low-permeability argillites", Environmental Earth Sciences, (2012). DOI:10.1007/s12665-012-1871-0
  • [3] Dultz, S., Simonyan, A.V., Pastrana, J., Behrens, H., Plötze, M., Rath, T., "Implications of pore space characteristics on diffusive transport in basalts and granites", Environmental Earth Sciences, 69: 969–985, (2013). DOI: 10.1007/s12665-012-1981-8
  • [4] Ishakoğlu, A., Boytaş, A. F.," Measurement and evaluation of saturations for water, ethanol and light non- aqueous phase liquid in a porous medium by gamma attenuation", Applied Radiation and Isotopes, 56: 60-606, (2002).
  • [5] Dullien, F.A.L., "Porous media, fluid transport and pore structure", Academic Press San Diego, 1-4, (1192).
  • [6] Alazmi, B., Vafai, K., "Analysis of variants within the porous media transport models”, Journal of Heat Transfer., 122: 303-326, (2000).
  • [7] Mann, R., El-Nafaty, U.A., "Probing internal structures of FCC catalysts particles: From paralel bundles to fractals", Studies in Surface Science and Catalysis, 100: 355-364, (1996).
  • [8] Rieckmann, C., Keil, F.J., "Multicomponent diffüsion and reaction in 3-D networks", Industrial& Engineeering Chemistry, ACS Publications, 3275-3281, (1997).
  • [9] Sahimi, M., "Flow and Transport in Porous Media and Fractured Rock: From Classical Methods to Modern Approaches", VCH, Weinheim, Germany, (1995).
  • [10] Fatt, I.," The network model of porous media I. Capillary pressure characteristics", Transactions of the AIME, 207:144–159, (1956). DOI: https://doi.org/10.2118/574-G
  • [11] Feng, X., Yin Y., "Geometry models of porous media based on Voronoi tessellations and their porosity–permeability relations", Computers & Mathematics with Applications, 72: 328-348, (2016).
  • [12] Kirkpatrick, S., "Percolation and conduction", Reviews of Modern Physics, 45(4): 574–588, (1973).
  • [13] Balberg I., "Recent developments in continuum percolation", Philosophical Magazine Part B, 56(6), 991-1003, (1987).
  • [14] Benham, G., Bickle, M., Neufeld, J., "Upscaling multiphase viscous-to-capillary transtions in the heterogeneous porous media", Journal of Fluid Mechanics, 911 A59, (2021). DOI:10.1017/jfm.2020.1134
  • [15] Dogu, T., Boz, N., Aydın, E., Oktar, N., Murtezaoglu, K., Dogu, G., "Drıft Studies fort he reaction and adsorption of alcohols and isobutylene on acidic resin catalysts and the mechanism of ETBE and MTBE synthesis”, Industrial & Engineering Chemistry Ressearch, 40: 5044-51, (2001).
  • [16] Simsek, V., Avcı, P., "Characterization and catalytic performance of modified sba-16 in liquid phase reaction", International Journal of Chemical Reactor Engineering, (2018). DOI: https://doi.org/10.1515/ijcre-2017-0246
  • [17] Simsek, V., "Investigation of catalytic sustainability of silica-based mesoporous acidic catalysts and ion-exchange resins in methyl acetate synthesis and characterizations of synthesized catalysts", Arabian Journal for Science and Engineering, 44: 5301-5310, (2019). DOI: 10.1007/s13369-018-3570-y
  • [18] Yang, A., Antrassian C., Kurtzman J., "Production of Dimethyl Ether (DME) for Transportation Fuel", Senior Design Reports (CBE) University of Pennsylvania Scholarly Commons, 4(21), 1-190, (2020).
  • [19] Dogu, T., Aydin, E., Boz, N., Murtezaoglu, K., Dogu, G., "Diffusion resistances and contribution of surface diffusion in TAME and TAEE production using Amberlyst - 15”, International Journal of Chemical Reactor Engineering, A6 1-9, (2003).
  • [20] Boz, N., Dogu T., Murtezaoglu K., Dogu, G., "Effect of hydrogen ion- Exchange capacity on activity of resin in tert-amyl-ethyl-ether synthesis", Applied Catalysis a General, 268: 175-182, (2004).
  • [21] IUPAC, "Manual of symbols and terminology", Pure Applied Chemistry, 31: 578, (1978).
  • [22] Jiang, Z., Van Dijke, M.J., Wu, K., Couples, G.D., Sorbie, K.S., Ma, J., "Stochastic Pore Network Generation from 3D Rock Images", Transport in Porous Media, 94: 571-593, (2012). DOI: 10.1007/s11242-011-9792-z
  • [23] Matthew, T.B., Karsten, E.T., Hjortso, M., "Coupling pore-scale Networks to continuum scale models od porous media", Computers & Gesciences, 33: 393-410, (2007).
  • [24] Woodsford, P.A., "The design and implementation of the GINO 3D graphics software package", Software-Practice and Experience, 1, 4, (1971).
  • [25] Rigby, S.P., Gladden, L. F., "Deconvelving pore shielding effects in mercury porosimetry data using NMR techniques", Chemical Engineering Science, 55: 5599-5612, (2000).
  • [26] Allamy, A., Mann, R., Holt, A., "Modeling of catalyst particle skin effects using a 3-D pore network model and quantitive microscopy", Chemical Engineering Science, 58(10): 1989-2000, (2003).
  • [27] Kzenzhek, O. S., "Capillary equilibrium in porous media with intersecting pores", Zhurnal Fizicheskoi Khimii, 36: 691, (1963).
  • [28] Sbaiti, B., "Modelling of oil bearing rock using a three dimensional network model", MSc. Thesis, University of Manchester Institue of Science and Technology, Manchester, 1-40, (1983).
  • [29] Golshan, H., "Development and application of stochastic pore structure models", Ph.D Thesis, University of Manchester Institue of Science and Technology, Manchester, 1- 75, (1979).
  • [30] URL, https://www.lenntech.com/Data-sheets/Dow-Amberlyst-35-dry-L.pdf, (19.04.2021).
  • [31] Mürtezaoğlu, K., "Further developments in the use of visualised porosimetry for PVC structure characterization", Ph.D. Thesis, University of Manchester Institue of Science and Technology, Manchester, 6-54, 65-104, (1994).
  • [32] Khalaf, K.M., "Characterisation of FFC catalyst particles using 3-D stochastic pore networks", Ph.D. Thesis, University of Manchester Institue of Science and Technology, Manchester, 1-100, (1998).
  • [33] Roudaki, S.J.M., "Application of three – dimensional stochastic pore network to zinc oxide particles", M.Sc. Dissertation, University of Manchester Institue of Science and Technology, Manchester, 1-40, (1989).
  • [34] Simsek, V., Oktar, N., Mürtezaoğlu, K., "Application of mercury porosimetry to three dimensional (3D) stochastic network model on ion exchange resins", 5th chemical engineering conference for collaborative research in eastern mediterranean countries -EMCC5 may 24-29, (2008).

3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs

Year 2023, Volume: 36 Issue: 3, 1001 - 1020, 01.09.2023
https://doi.org/10.35378/gujs.1011056

Abstract

In the present paper, the investigation was focused on the physical characterization and determination of porosity for an ion exchange catalyst called Amberlyst-35, which produces environmentally benign gasoline using 3D network modeling (3DNM). In addition, the effect of the different pore size distributions (PSD) has been investigated in porous media (PM). First, the mercury porosimetry (MPo) experiment was carried out to determine the porosity of the Amberlyst-35. Second, the KALINET program was run by Compact Visual Fortran (CVF) and Graphical Input/Output (GINO) for modeling porous structures. Then, the SECTION program was used for different porous 3D random images. The theoretical penetration curve was drawn using data obtained from the KALINET program and fitted to the experimental penetration values of Amberlyst-35 by changing the number of pores in each pressure interval of the PSD. The PSD was a 3D network model size of (N) = 30x30x30, 40x40x40, 50x50x50, which included 83,700-196,800-382,500 pores, respectively. On the other hand, various sections of the 3D stochastic images of the pore network were obtained from the SECTION program. Finally, 3D network images were drawn by the KALINET3D computer program. The MPo method has been applied using computer programs (with desktop computers). Moreover, it was found that the same results were obtained for both the theoretical and experimental data of MPo.

References

  • [1] Simsek, V., "Application of mercury porosimetry to three dimensional(3D) stochastic network model and researching network size effect on structure of porous media", MSc Thesis, Gazi University Graduate School of Natural and Applied Sciences, (2008).
  • [2] Huysmans, M., Dassargues, A., "The effect of heterogeneity of diffusion parameters on chloride transport in low-permeability argillites", Environmental Earth Sciences, (2012). DOI:10.1007/s12665-012-1871-0
  • [3] Dultz, S., Simonyan, A.V., Pastrana, J., Behrens, H., Plötze, M., Rath, T., "Implications of pore space characteristics on diffusive transport in basalts and granites", Environmental Earth Sciences, 69: 969–985, (2013). DOI: 10.1007/s12665-012-1981-8
  • [4] Ishakoğlu, A., Boytaş, A. F.," Measurement and evaluation of saturations for water, ethanol and light non- aqueous phase liquid in a porous medium by gamma attenuation", Applied Radiation and Isotopes, 56: 60-606, (2002).
  • [5] Dullien, F.A.L., "Porous media, fluid transport and pore structure", Academic Press San Diego, 1-4, (1192).
  • [6] Alazmi, B., Vafai, K., "Analysis of variants within the porous media transport models”, Journal of Heat Transfer., 122: 303-326, (2000).
  • [7] Mann, R., El-Nafaty, U.A., "Probing internal structures of FCC catalysts particles: From paralel bundles to fractals", Studies in Surface Science and Catalysis, 100: 355-364, (1996).
  • [8] Rieckmann, C., Keil, F.J., "Multicomponent diffüsion and reaction in 3-D networks", Industrial& Engineeering Chemistry, ACS Publications, 3275-3281, (1997).
  • [9] Sahimi, M., "Flow and Transport in Porous Media and Fractured Rock: From Classical Methods to Modern Approaches", VCH, Weinheim, Germany, (1995).
  • [10] Fatt, I.," The network model of porous media I. Capillary pressure characteristics", Transactions of the AIME, 207:144–159, (1956). DOI: https://doi.org/10.2118/574-G
  • [11] Feng, X., Yin Y., "Geometry models of porous media based on Voronoi tessellations and their porosity–permeability relations", Computers & Mathematics with Applications, 72: 328-348, (2016).
  • [12] Kirkpatrick, S., "Percolation and conduction", Reviews of Modern Physics, 45(4): 574–588, (1973).
  • [13] Balberg I., "Recent developments in continuum percolation", Philosophical Magazine Part B, 56(6), 991-1003, (1987).
  • [14] Benham, G., Bickle, M., Neufeld, J., "Upscaling multiphase viscous-to-capillary transtions in the heterogeneous porous media", Journal of Fluid Mechanics, 911 A59, (2021). DOI:10.1017/jfm.2020.1134
  • [15] Dogu, T., Boz, N., Aydın, E., Oktar, N., Murtezaoglu, K., Dogu, G., "Drıft Studies fort he reaction and adsorption of alcohols and isobutylene on acidic resin catalysts and the mechanism of ETBE and MTBE synthesis”, Industrial & Engineering Chemistry Ressearch, 40: 5044-51, (2001).
  • [16] Simsek, V., Avcı, P., "Characterization and catalytic performance of modified sba-16 in liquid phase reaction", International Journal of Chemical Reactor Engineering, (2018). DOI: https://doi.org/10.1515/ijcre-2017-0246
  • [17] Simsek, V., "Investigation of catalytic sustainability of silica-based mesoporous acidic catalysts and ion-exchange resins in methyl acetate synthesis and characterizations of synthesized catalysts", Arabian Journal for Science and Engineering, 44: 5301-5310, (2019). DOI: 10.1007/s13369-018-3570-y
  • [18] Yang, A., Antrassian C., Kurtzman J., "Production of Dimethyl Ether (DME) for Transportation Fuel", Senior Design Reports (CBE) University of Pennsylvania Scholarly Commons, 4(21), 1-190, (2020).
  • [19] Dogu, T., Aydin, E., Boz, N., Murtezaoglu, K., Dogu, G., "Diffusion resistances and contribution of surface diffusion in TAME and TAEE production using Amberlyst - 15”, International Journal of Chemical Reactor Engineering, A6 1-9, (2003).
  • [20] Boz, N., Dogu T., Murtezaoglu K., Dogu, G., "Effect of hydrogen ion- Exchange capacity on activity of resin in tert-amyl-ethyl-ether synthesis", Applied Catalysis a General, 268: 175-182, (2004).
  • [21] IUPAC, "Manual of symbols and terminology", Pure Applied Chemistry, 31: 578, (1978).
  • [22] Jiang, Z., Van Dijke, M.J., Wu, K., Couples, G.D., Sorbie, K.S., Ma, J., "Stochastic Pore Network Generation from 3D Rock Images", Transport in Porous Media, 94: 571-593, (2012). DOI: 10.1007/s11242-011-9792-z
  • [23] Matthew, T.B., Karsten, E.T., Hjortso, M., "Coupling pore-scale Networks to continuum scale models od porous media", Computers & Gesciences, 33: 393-410, (2007).
  • [24] Woodsford, P.A., "The design and implementation of the GINO 3D graphics software package", Software-Practice and Experience, 1, 4, (1971).
  • [25] Rigby, S.P., Gladden, L. F., "Deconvelving pore shielding effects in mercury porosimetry data using NMR techniques", Chemical Engineering Science, 55: 5599-5612, (2000).
  • [26] Allamy, A., Mann, R., Holt, A., "Modeling of catalyst particle skin effects using a 3-D pore network model and quantitive microscopy", Chemical Engineering Science, 58(10): 1989-2000, (2003).
  • [27] Kzenzhek, O. S., "Capillary equilibrium in porous media with intersecting pores", Zhurnal Fizicheskoi Khimii, 36: 691, (1963).
  • [28] Sbaiti, B., "Modelling of oil bearing rock using a three dimensional network model", MSc. Thesis, University of Manchester Institue of Science and Technology, Manchester, 1-40, (1983).
  • [29] Golshan, H., "Development and application of stochastic pore structure models", Ph.D Thesis, University of Manchester Institue of Science and Technology, Manchester, 1- 75, (1979).
  • [30] URL, https://www.lenntech.com/Data-sheets/Dow-Amberlyst-35-dry-L.pdf, (19.04.2021).
  • [31] Mürtezaoğlu, K., "Further developments in the use of visualised porosimetry for PVC structure characterization", Ph.D. Thesis, University of Manchester Institue of Science and Technology, Manchester, 6-54, 65-104, (1994).
  • [32] Khalaf, K.M., "Characterisation of FFC catalyst particles using 3-D stochastic pore networks", Ph.D. Thesis, University of Manchester Institue of Science and Technology, Manchester, 1-100, (1998).
  • [33] Roudaki, S.J.M., "Application of three – dimensional stochastic pore network to zinc oxide particles", M.Sc. Dissertation, University of Manchester Institue of Science and Technology, Manchester, 1-40, (1989).
  • [34] Simsek, V., Oktar, N., Mürtezaoğlu, K., "Application of mercury porosimetry to three dimensional (3D) stochastic network model on ion exchange resins", 5th chemical engineering conference for collaborative research in eastern mediterranean countries -EMCC5 may 24-29, (2008).
There are 34 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemical Engineering
Authors

Veli Şimşek 0000-0002-3518-1572

Kırali Murtezaoğlu 0000-0002-0810-2816

Publication Date September 1, 2023
Published in Issue Year 2023 Volume: 36 Issue: 3

Cite

APA Şimşek, V., & Murtezaoğlu, K. (2023). 3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs. Gazi University Journal of Science, 36(3), 1001-1020. https://doi.org/10.35378/gujs.1011056
AMA Şimşek V, Murtezaoğlu K. 3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs. Gazi University Journal of Science. September 2023;36(3):1001-1020. doi:10.35378/gujs.1011056
Chicago Şimşek, Veli, and Kırali Murtezaoğlu. “3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 With Computer Programs”. Gazi University Journal of Science 36, no. 3 (September 2023): 1001-20. https://doi.org/10.35378/gujs.1011056.
EndNote Şimşek V, Murtezaoğlu K (September 1, 2023) 3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs. Gazi University Journal of Science 36 3 1001–1020.
IEEE V. Şimşek and K. Murtezaoğlu, “3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs”, Gazi University Journal of Science, vol. 36, no. 3, pp. 1001–1020, 2023, doi: 10.35378/gujs.1011056.
ISNAD Şimşek, Veli - Murtezaoğlu, Kırali. “3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 With Computer Programs”. Gazi University Journal of Science 36/3 (September 2023), 1001-1020. https://doi.org/10.35378/gujs.1011056.
JAMA Şimşek V, Murtezaoğlu K. 3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs. Gazi University Journal of Science. 2023;36:1001–1020.
MLA Şimşek, Veli and Kırali Murtezaoğlu. “3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 With Computer Programs”. Gazi University Journal of Science, vol. 36, no. 3, 2023, pp. 1001-20, doi:10.35378/gujs.1011056.
Vancouver Şimşek V, Murtezaoğlu K. 3D Stochastic Network Modeling and Investigation of Network Size Effect on the Porous Media Structure of Ion Exchange Catalyst Amberlyst-35 with Computer Programs. Gazi University Journal of Science. 2023;36(3):1001-20.